diff --git a/ChangeLog.rst b/ChangeLog.rst index 57d34e3..76e7334 100644 --- a/ChangeLog.rst +++ b/ChangeLog.rst @@ -36,7 +36,7 @@ Modified: as 1e-7 (relative) in Avogadro number, Planck constant, J/eV, electron radius, electron mass, neutron mass and atomic mass constant. * Updated bound coherent scattering length for H-1, H-2, He-4, C-12, - O-16, O-17, O-18, Sn-119, Sm-154, Eu-153, Pb-207, Bi-209 + O-16, O-17, O-18, Sn-119, Sm-154, Eu-153, Ir-191, Ir-193, Pb-207, Bi-209 * Updated total cross section for He, Kr, Xe * Use log-log interpolation for X-ray f'' diff --git a/periodictable/nsf.py b/periodictable/nsf.py index a0d2558..dde8252 100644 --- a/periodictable/nsf.py +++ b/periodictable/nsf.py @@ -113,6 +113,8 @@ 119Sn b_c 6.28(3) => 6.2239(13) [1] 154Sm b_c 8.0(1.0) => 8.97(6) [4] 153Eu b_c 8.22(12) => 8.85(3) [4] + 191Ir b_c => 12.1(9) [6] + 193Ir b_c => 9.71(18) [6] 207Pb b_c 9.286(16) => 9.4024(13) [1] 209Bi b_c 8.532(2) => 8.5242(18) [1] @@ -126,6 +128,7 @@ [3] Haun (2020) 10.1103/PhysRevLett.124.012501 [4] Kohlmann (2016) 10.1515/zkri-2016-1984 [5] Haddock (2019) 10.1103/PhysRevC.100.064002 + [6] Hannon (2018) 10.1107/S1600576718006064 .. [#Rauch2003] Rauch, H. and Waschkowski, W. (2003) Neutron Scattering Lengths in ILL @@ -594,6 +597,18 @@ def init(table, reload=False): b_c_i = -nsf.absorption/(2000*ABSORPTION_WAVELENGTH) nsf.b_c_complex = b_c + 1j*b_c_i + if not np.isnan(b_c): + # Ir-191 and Ir-193 don't list scattering cross sections so deduce + # them from the bound coherent cross section. Since these are both + # odd isotopes there ought to be some incoherent scattering, but + # zero is well within the uncertainty measured in bulk Ir. + if nsf.coherent is None: + nsf.coherent = 4*pi/100*abs(nsf.b_c_complex)**2 + if nsf.incoherent is None: + nsf.incoherent = 0 + if nsf.total is None: + nsf.total = nsf.coherent + nsf.incoherent + parts = columns[0].split('-') Z = int(parts[0]) symbol = parts[1] @@ -1623,8 +1638,8 @@ def sld_plot(table=None): 76-Os-190,26.4,0,11.4(3),,,,15.2(8),0,15.2(8),13.1(3) 76-Os-192,41,0,11.9(4),,,,16.6(1.2),0,16.6(1.2),2.0(1) 77-Ir,,,10.6(3),,,,14.1(8),0.0(3.0),14.0(3.0),425.0(2.0) -77-Ir-191,37.4,3/2,,,,,,,,954.0(10.0) -77-Ir-193,62.6,3/2,,,,,,,,111.0(5.0) +77-Ir-191,37.4,3/2,12.1(9),,,,,,,954.0(10.0) +77-Ir-193,62.6,3/2,9.71(18),,,,,,,111.0(5.0) 78-Pt,,,9.60(1),,,,11.58(2),0.13(11),11.71(11),10.3(3) 78-Pt-190,0.01,0,9.0(1.0),,,,10.0(2.0),0,10.0(2.0),152.0(4.0) 78-Pt-192,1.78,0,9.9(5),,,,12.3(1.2),0,12.3(1.2),10.0(2.5)