diff --git a/doc/whats-new.rst b/doc/whats-new.rst
index 70aef4acf3e..760cab51552 100644
--- a/doc/whats-new.rst
+++ b/doc/whats-new.rst
@@ -63,6 +63,12 @@ Bug Fixes
 - :py:func:`polyval` now propagates ``NaN`` for ``NaT`` entries in ``timedelta64``
   coordinates instead of returning a large sentinel value (:issue:`11462`).
   By `Dipak Chaudhari <https://github.com/dchaudhari7177>`_.
+- :py:func:`align` now raises ``AlignmentError`` when one index would reorder a
+  dimension that another, already aligned, index shares. Previously an index
+  requiring no reindexing was skipped by the conflict check, so conflicting
+  indexes aligned silently and the mismatched index was used to combine the data
+  (:issue:`10714`).
+  By `Kayvan Zahiri <https://github.com/Kayvan-Zahiri>`_.
 
 
 Documentation
diff --git a/xarray/structure/alignment.py b/xarray/structure/alignment.py
index f5d61e63409..6acdeb2bd85 100644
--- a/xarray/structure/alignment.py
+++ b/xarray/structure/alignment.py
@@ -550,6 +550,19 @@ def _get_dim_pos_indexers(
         dim_pos_indexers: dict[Hashable, Any] = {}
         dim_index: dict[Hashable, Index] = {}
 
+        # An index that needs no reindexing is equal across all objects, so it pins
+        # its dimensions in place. It never produces an indexer of its own, which
+        # means the conflict check below would otherwise never see it and a second
+        # index sharing the same dimension could silently reorder it.
+        unchanged_dim_index: dict[Hashable, Index] = {}
+        for key in self.aligned_indexes:
+            obj_idx = matching_indexes.get(key)
+            if obj_idx is not None and not self.reindex[key]:
+                for dim in {
+                    d for var in self.aligned_index_vars[key].values() for d in var.dims
+                }:
+                    unchanged_dim_index.setdefault(dim, obj_idx)
+
         for key, aligned_idx in self.aligned_indexes.items():
             obj_idx = matching_indexes.get(key)
             if obj_idx is not None and self.reindex[key]:
@@ -562,6 +575,19 @@ def _get_dim_pos_indexers(
                             "wrong results returned by the `reindex_like` method of this index:\n"
                             f"{obj_idx!r}"
                         )
+                    idxer_arr = np.asarray(idxer)
+                    reorders = not (
+                        idxer_arr.ndim == 1
+                        and np.array_equal(idxer_arr, np.arange(idxer_arr.size))
+                    )
+                    if dim in unchanged_dim_index and reorders:
+                        raise AlignmentError(
+                            f"cannot reindex or align along dimension {dim!r} because "
+                            "it would reorder another index that is already aligned along "
+                            "that dimension\n"
+                            f"first index: {obj_idx!r}\n"
+                            f"second index: {unchanged_dim_index[dim]!r}\n"
+                        )
                     if dim in dim_pos_indexers and not np.array_equal(
                         idxer, dim_pos_indexers[dim]
                     ):
diff --git a/xarray/tests/test_dataset.py b/xarray/tests/test_dataset.py
index a7178bba512..f54f223f9ec 100644
--- a/xarray/tests/test_dataset.py
+++ b/xarray/tests/test_dataset.py
@@ -2729,6 +2729,23 @@ def test_align_multiple_indexes_common_dim(self) -> None:
         with pytest.raises(AlignmentError, match=r".*conflicting re-indexers"):
             align(a, c)
 
+    def test_align_multiple_indexes_common_dim_no_reindex(self) -> None:
+        # An index that needs no reindexing produces no re-indexer, so it used to
+        # escape the conflict check entirely and a second index sharing its
+        # dimension could silently reorder it. See GH10714.
+        a = Dataset(coords={"x": [1, 2, 3], "xb": ("x", [4, 5, 6])}).set_xindex("xb")
+        # "x" is equal in both and needs no reindexing; only "xb" conflicts
+        b = Dataset(coords={"x": [1, 2, 3], "xb": ("x", [4, 6, 5])}).set_xindex("xb")
+
+        with pytest.raises(AlignmentError, match=r".*would reorder another index"):
+            align(a, b)
+
+        # reordering a dimension is still fine when nothing else pins it
+        d = Dataset(coords={"x": [3, 1, 2], "xb": ("x", [6, 4, 5])}).set_xindex("xb")
+        (a2, d2) = align(a, d)
+        assert_identical(a2, a, check_default_indexes=False)
+        assert_identical(d2, a, check_default_indexes=False)
+
     def test_align_conflicting_indexes(self) -> None:
         class CustomIndex(PandasIndex): ...