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CM_ChemRates_mod.f90
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CM_ChemRates_mod.f90
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! Generated by GenChem.py - DO NOT EDIT
! scheme(s) EmChem16x ShipNOx BVOC_EmChem16x Aqueous_EmChem16x Aero2017nx VBS_EmChem16x FFireInert SeaSalt DustExtended Ash_EmChem16x
module ChemRates_mod
use AeroConstants_mod ! => AERO%PM etc, ...
use AeroFunctions_mod ! => UptakeRates, ...
use ChemDims_mod ! => NSPEC_TOT, NCHEMRATES, ....
use ChemFunctions_mod ! => IUPAC_troe, RiemerN2O5, ....
use ChemSpecs_mod ! => PINALD, .... for FgasJ08
use DefPhotolysis_mod ! => IDNO2 etc.
use ZchemData_mod ! => rct
implicit none
private
character(len=*),parameter, public :: CM_schemes_ChemRates = " EmChem16x ShipNOx BVOC_EmChem16x Aqueous_EmChem16x Aero2017nx VBS_EmChem16x FFireInert SeaSalt DustExtended Ash_EmChem16x"
public :: setChemRates
public :: setPhotolUsed
! Photolysis rates
integer, save, public, dimension(NPHOTOLRATES) :: photol_used
contains
subroutine setPhotolUsed()
photol_used = (/ &
IDCH3O2H &
, IDHCHO_H &
, IDMEK &
, IDCH3CHO &
, IDNO2 &
, IDO3_O1D &
, IDO3_O3P &
, IDH2O2 &
, IDNO3_NO2 &
, IDHNO3 &
, IDHO2NO2 &
, IDHCHO_H2 &
, IDCHOCHO &
, IDRCOCHO &
/)
end subroutine setPhotolUsed
subroutine setChemRates()
!integer, intent(in) :: debug_level
rct(1,:) = ((5.681e-34*EXP(-2.6*(LOG(TEMP/300))))*O2)*M
rct(2,:) = (2.15e-11*EXP(110.0*TINV))*N2
rct(3,:) = (3.2e-11*EXP(67.0*TINV))*O2
rct(4,:) = (2.14e-10)*H2O
rct(5,:) = 1.4e-12*EXP(-1310.0*TINV)
rct(6,:) = 1.4e-13*EXP(-2470.0*TINV)
rct(7,:) = 1.7e-12*EXP(-940.0*TINV)
rct(8,:) = 2.03e-16*EXP(-4.57*(LOG(300/TEMP)))*EXP(693.0*TINV)
rct(9,:) = 1.8e-11*EXP(110.0*TINV)
rct(10,:) = (3.3e-39*EXP(530*TINV))*O2
rct(11,:) = 3.6e-12*EXP(270.0*TINV)
rct(12,:) = 4.5e-14*EXP(-1260.0*TINV)
rct(13,:) = 4.8e-11*EXP(250.0*TINV)
rct(14,:) = 2.9e-12*EXP(-160.0*TINV)
rct(15,:) = 7.7e-12*EXP(-2100.0*TINV)
rct(16,:) = (KMT3(2.4e-14, &
& 460.0, &
& 6.5e-34, &
& 1335.0, &
& 2.7e-17, &
& 2199.0))
rct(17,:) = (((1.4e-31*M*(TEMP/300)**(-3.1))*(4.0e-12))*(10**(LOG10(0.4) &
& /(1+(LOG10(((1.4e-31*M*(TEMP/300)**(-3.1))/(4.0e-12))) &
& /(0.75-1.27*(LOG10(0.4))))**2)))/((1.4e-31*M*(TEMP/300) &
& **(-3.1))+(4.0e-12)))
rct(18,:) = (((4.10e-05*M*EXP(-10650/TEMP))*(6.0e+15*EXP(-11170/TEMP))) &
& *(10**(LOG10(0.4)/(1+(LOG10(((4.10e-05*M*EXP(-10650/TEMP)) &
& /(6.0e+15*EXP(-11170/TEMP))))/(0.75-1.27*(LOG10(0.4)))) &
& **2)))/((4.10e-05*M*EXP(-10650/TEMP)) &
& +(6.0e+15*EXP(-11170/TEMP))))
rct(19,:) = 3.2e-13*EXP(690/TEMP)
rct(20,:) = ((1.0+1.4e-21*H2O*EXP(2200.0*TINV)))*2.2e-13*EXP(600.0*TINV)
rct(21,:) = (((1.0+1.4e-21*H2O*EXP(2200.0*TINV))) &
& *1.9e-33*EXP(980.0*TINV))*M
rct(22,:) = 2.5e-12*EXP(260.0*TINV)
rct(23,:) = 1.85e-20*EXP(2.82*LOG(TEMP))*EXP(-987.0*TINV)
rct(24,:) = (3.43e-33)*M
rct(25,:) = 2.3e-12*EXP(360.0*TINV)
rct(26,:) = 7.4e-13*EXP(-520.0*TINV)
rct(27,:) = 1.03e-13*EXP(365.0*TINV)-7.4e-13*EXP(-520.0*TINV)
rct(28,:) = 6.38e-18*(TEMP**2)*EXP(144.0*TINV)
rct(29,:) = 3.8e-13*EXP(780.0*TINV)
rct(30,:) = 5.3e-12*EXP(190.0*TINV)
rct(31,:) = 1.25e-17*(TEMP**2)*EXP(615.0*TINV)
rct(32,:) = 2.0e-12*EXP(-2440.0*TINV)
rct(33,:) = 6.9e-12*EXP(-1000.0*TINV)
rct(34,:) = 2.55e-12*EXP(380.0*TINV)
rct(35,:) = 3.8e-13*EXP(900.0*TINV)
rct(36,:) = (1.9e-12*EXP(190.0*TINV))
rct(37,:) = 4.4e-12*EXP(365.0*TINV)
rct(38,:) = 7.5e-12*EXP(290.0*TINV)
rct(39,:) = 2.0e-12*EXP(500.0*TINV)
rct(40,:) = 2.9e-12*EXP(500.0*TINV)
rct(41,:) = 5.2e-13*EXP(980.0*TINV)
rct(42,:) = 1.9e-12*EXP(190.0*TINV)
rct(43,:) = 6.7e-18*(TEMP**2)*EXP(511.0*TINV)
rct(44,:) = 2.03e-17*(TEMP**2)*EXP(78.0*TINV)
rct(45,:) = (2.54e-12*EXP(360.0*TINV))
rct(46,:) = 0.625*(2.91e-13*EXP(1300.0*TINV))
rct(47,:) = 2.53e-18*(TEMP**2)*EXP(503.0*TINV)
rct(48,:) = 9.1e-15*EXP(-2580.0*TINV)
rct(49,:) = 5.5e-15*EXP(-1880.0*TINV)
rct(50,:) = 0.52*(2.91e-13*EXP(1300.0*TINV))
rct(51,:) = 0.859*(2.91e-13*EXP(1300.0*TINV))
rct(52,:) = 0.706*(2.91e-13*EXP(1300.0*TINV))
rct(53,:) = 6.6e-18*(TEMP**2)*EXP(820.0*TINV)
rct(54,:) = 1.9e-12*EXP(575.0*TINV)
rct(55,:) = 2.7e-11*EXP(390*TINV)
rct(56,:) = 1.03e-14*EXP(-1995*TINV)*0.333
rct(57,:) = 3.15e-12*EXP(-450*TINV)
rct(58,:) = (2.54e-12*EXP(360.0*TINV))*0.9
rct(59,:) = (2.54e-12*EXP(360.0*TINV))*0.1
rct(60,:) = (2.91e-13*EXP(1300.0*TINV))*0.706
rct(61,:) = 8.94e-11*0.9
rct(62,:) = 8.94e-11*0.1
rct(63,:) = 9.20e-17*0.67
rct(64,:) = 9.20e-17*0.33
rct(65,:) = 1.30e-12*EXP(610.0*TINV)
rct(66,:) = 4.00e-12*EXP(380.0*TINV)
rct(67,:) = 2.13e-16*EXP(-1520.0*TINV)
rct(68,:) = 3.50e-16*EXP(-2100.0*TINV)
rct(69,:) = (2.54e-12*EXP(360.0*TINV))*0.5
rct(70,:) = (2.91e-13*EXP(1300.0*TINV))*0.625
rct(71,:) = 1.60e-12*EXP(305*TINV)
rct(72,:) = (((3.28e-28*M*(TEMP/300)**(-6.87))*(1.125e-11*(TEMP/300) &
& **(-1.105)))*(10**(LOG10(0.30) &
& /(1+(LOG10(((3.28e-28*M*(TEMP/300)**(-6.87)) &
& /(1.125e-11*(TEMP/300)**(-1.105)))) &
& /(0.75-1.27*(LOG10(0.30))))**2)))/((3.28e-28*M*(TEMP/300) &
& **(-6.87))+(1.125e-11*(TEMP/300)**(-1.105))))*0.107
rct(73,:) = (((1.10e-05*M*EXP(-10100/TEMP))*(1.90e17*EXP(-14100/TEMP))) &
& *(10**(LOG10(0.30)/(1+(LOG10(((1.10e-05*M*EXP(-10100/TEMP)) &
& /(1.90e17*EXP(-14100/TEMP))))/(0.75-1.27*(LOG10(0.30)))) &
& **2)))/((1.10e-05*M*EXP(-10100/TEMP)) &
& +(1.90e17*EXP(-14100/TEMP))))
rct(74,:) = 1.88e09*EXP(-7261*TINV)*0.052
rct(75,:) = 1.45e12*EXP(-10688*TINV)
rct(76,:) = (((1.0e-31*M*(TEMP/300)**(-1.6))*(5.0e-11*(TEMP/300) &
& **(-0.3)))*(10**(LOG10(0.85) &
& /(1+(LOG10(((1.0e-31*M*(TEMP/300)**(-1.6)) &
& /(5.0e-11*(TEMP/300)**(-0.3))))/(0.75-1.27*(LOG10(0.85)))) &
& **2)))/((1.0e-31*M*(TEMP/300)**(-1.6))+(5.0e-11*(TEMP/300) &
& **(-0.3))))
rct(77,:) = (((3.6e-30*M*(TEMP/300)**(-4.1))*(1.9e-12*(TEMP/300)**0.2)) &
& *(10**(LOG10(0.35)/(1+(LOG10(((3.6e-30*M*(TEMP/300)**(-4.1)) &
& /(1.9e-12*(TEMP/300)**0.2)))/(0.75-1.27*(LOG10(0.35)))) &
& **2)))/((3.6e-30*M*(TEMP/300)**(-4.1))+(1.9e-12*(TEMP/300) &
& **0.2)))
rct(78,:) = (((1.3e-3*M*(TEMP/300)**(-3.5)*EXP(-11000/TEMP)) &
& *(9.7e+14*(TEMP/300)**0.1*EXP(-11080/TEMP))) &
& *(10**(LOG10(0.35)/(1+(LOG10(((1.3e-3*M*(TEMP/300)**(-3.5) &
& *EXP(-11000/TEMP))/(9.7e+14*(TEMP/300) &
& **0.1*EXP(-11080/TEMP))))/(0.75-1.27*(LOG10(0.35))))**2))) &
& /((1.3e-3*M*(TEMP/300)**(-3.5)*EXP(-11000/TEMP)) &
& +(9.7e+14*(TEMP/300)**0.1*EXP(-11080/TEMP))))
rct(79,:) = (((3.2e-30*M*(TEMP/300)**(-4.5))*(3.0e-11)) &
& *(10**(LOG10(0.41)/(1+(LOG10(((3.2e-30*M*(TEMP/300)**(-4.5)) &
& /(3.0e-11)))/(0.75-1.27*(LOG10(0.41))))**2))) &
& /((3.2e-30*M*(TEMP/300)**(-4.5))+(3.0e-11)))
rct(80,:) = (((3.28e-28*M*(TEMP/300)**(-6.87))*(1.125e-11*(TEMP/300) &
& **(-1.105)))*(10**(LOG10(0.30) &
& /(1+(LOG10(((3.28e-28*M*(TEMP/300)**(-6.87)) &
& /(1.125e-11*(TEMP/300)**(-1.105)))) &
& /(0.75-1.27*(LOG10(0.30))))**2)))/((3.28e-28*M*(TEMP/300) &
& **(-6.87))+(1.125e-11*(TEMP/300)**(-1.105))))
rct(81,:) = (((8.6e-29*M*(TEMP/300)**(-3.1))*(9.0e-12*(TEMP/300) &
& **(-0.85)))*(10**(LOG10(0.48) &
& /(1+(LOG10(((8.6e-29*M*(TEMP/300)**(-3.1)) &
& /(9.0e-12*(TEMP/300)**(-0.85))))/(0.75-1.27*(LOG10(0.48)))) &
& **2)))/((8.6e-29*M*(TEMP/300)**(-3.1))+(9.0e-12*(TEMP/300) &
& **(-0.85))))
rct(82,:) = (((8e-27*M*(TEMP/300)**(-3.5))*(3.0e-11*(TEMP/300)**(-1))) &
& *(10**(LOG10(0.5)/(1+(LOG10(((8e-27*M*(TEMP/300)**(-3.5)) &
& /(3.0e-11*(TEMP/300)**(-1))))/(0.75-1.27*(LOG10(0.5)))) &
& **2)))/((8e-27*M*(TEMP/300)**(-3.5))+(3.0e-11*(TEMP/300) &
& **(-1))))
rct(83,:) = (((7.4e-31*M*(TEMP/300)**(-2.4))*(3.3e-11*(TEMP/300) &
& **(-0.3)))*(10**(LOG10(0.81) &
& /(1+(LOG10(((7.4e-31*M*(TEMP/300)**(-2.4)) &
& /(3.3e-11*(TEMP/300)**(-0.3))))/(0.75-1.27*(LOG10(0.81)))) &
& **2)))/((7.4e-31*M*(TEMP/300)**(-2.4))+(3.3e-11*(TEMP/300) &
& **(-0.3))))
rct(84,:) = 1.20e-11*EXP(440*TINV)
rct(85,:) = 2.38e-11*EXP(357*TINV)
rct(86,:) = 1.20e-11*EXP(440*TINV)*3.29
rct(87,:) = 7.5e-13*EXP(700*TINV)
rct(88,:) = 3.8e-12*EXP(200*TINV)
rct(89,:) = 8.05e-16*EXP(-640*TINV)
rct(90,:) = 1.35e-15*EXP(-1270*TINV)
rct(91,:) = 8.05e-16*EXP(-640*TINV)*3.34
rct(92,:) = 1.20e-12*EXP(490*TINV)
rct(93,:) = 1.20e-12*EXP(490*TINV)*2.249
rct(94,:) = HYDROLYSISN2O5()
rct(95,:) = UPTAKERATE(CNO3, &
& GAM=0.001, &
& S=S_M2M3(AERO%PM, &
& :))
rct(96,:) = UPTAKERATE(CHNO3, &
& GAM=0.1, &
& S=S_M2M3(AERO%DU_C, &
& :))
rct(97,:) = UPTAKERATE(CHNO3, &
& GAM=0.01, &
& S=S_M2M3(AERO%SS_C, &
& :))
rct(98,:) = UPTAKERATE(CHO2, &
& GAM=0.2, &
& S=S_M2M3(AERO%PM, &
& :))
rct(99,:) = 1.2e-12*EXP(490.0*TINV)
rct(100,:) = 4.0e-12*FGAS(ASOC_UG1, &
& :)
rct(101,:) = 4.0e-12*FGAS(ASOC_UG10, &
& :)
rct(102,:) = 4.0e-12*FGAS(ASOC_UG1e2, &
& :)
rct(103,:) = 4.0e-12*FGAS(ASOC_UG1e3, &
& :)
rct(104,:) = 4.0e-12*FGAS(NON_C_ASOA_UG1, &
& :)
rct(105,:) = 4.0e-12*FGAS(NON_C_ASOA_UG10, &
& :)
rct(106,:) = 4.0e-12*FGAS(NON_C_ASOA_UG1e2, &
& :)
rct(107,:) = 4.0e-12*FGAS(NON_C_ASOA_UG1e3, &
& :)
rct(108,:) = 4.0e-12*FGAS(BSOC_UG1, &
& :)
rct(109,:) = 4.0e-12*FGAS(BSOC_UG10, &
& :)
rct(110,:) = 4.0e-12*FGAS(BSOC_UG1e2, &
& :)
rct(111,:) = 4.0e-12*FGAS(BSOC_UG1e3, &
& :)
rct(112,:) = 4.0e-12*FGAS(NON_C_BSOA_UG1, &
& :)
rct(113,:) = 4.0e-12*FGAS(NON_C_BSOA_UG10, &
& :)
rct(114,:) = 4.0e-12*FGAS(NON_C_BSOA_UG1e2, &
& :)
rct(115,:) = 4.0e-12*FGAS(NON_C_BSOA_UG1e3, &
& :)
rct(116,:) = EC_AGEING_RATE()
rct(117,:) = 1.44e-13+M*3.43e-33
end subroutine setChemRates
end module ChemRates_mod