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The upper bound for b is 0, while iminuit fits it to: b = -0.017 +/- 0.052
When setting the starting value for b to -0.1, the scipy fit converges and is able to calculate the errors.
The underlying issue might be, that scipy is unable to calculate uncertainties, once the 1sigma interval is outside the parameter limits. iminuit does it anyway.
This example https://gist.github.com/cverstege/1e085a6c6349399a5fa957628675794c yields NaN as parameter errors.
Fitting with iminuit seems to work.
This should be investigated either way.
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